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Preface 1. Introduction to Shape-Selective Catalysis, Chunshan Song, Juan M. Garcs, and Yoshihuro Sugi GENERAL OVERVIEW 2. The Emergence of Shape-Selective Catalysis: Adventure, Basic Science, and Technology, Paul B. Weisz 3. Recent Advances in Shape-Selective Catalysis and Its Industrial Applications, Nai Y. Chen CATALYSIS OF ORGANIC REACTIONS 4. Organic Catalysis over Zeolites and Other Molecular Sieves: Shape-Selective Effects in Catalytic Transformations, Paul B. Venuto 5. Highly Efficient and Regioselective Cyclization Catalyzed by TS-1, Asim Bhaumik and Takashi Tatsumi 6. Oxidation of Alkanes Catalyzed by Different Octahedral Molecular Sieves, Guan-Guang Xia et al. METHANOL CONVERSION TO GASOLINE AND OLEFINS 7. The Methanol-to-Hydrocarbons Reaction: A Mechanistic Perspective, Clarence D. Chang 8. Highly Selective Synthesis of Light Olefins from Methanol Using Metal-Incorporated Silicoaluminophosphate Catalysts, Tomoyuki Inui 9. Role of Shape Selectivity in n-Heptane Cracking and Aromatization Reaction on Modified ZSM-5, T. S. R. Prasada Rao et al. 10. Shape Selectivity for Alkane Dehydrocyclization with Pt Silicalite Catalysts, Yuguo Wang et al. CONVERSION OF MONOCYCLIC HYDROCARBONS 11. MFI-Type Metallosilicates as Useful Tools to Clarify What Determines the Shape Selectivity of ZSM-5 Zeolites, T. Komatsu, J.-H. Kim, and T. Yashima 12. What Preferentially Determines the para Shape Selectivity: Diffusion of Molecules or External Surface Acidity, Miki Niwa, Takehisa Kunieda, and Jong-Ho Kim 13. Dispersion of Oxides on HZSM-5 and Threshold Effect on Shape-Selective Methylation of Toluene, Youchang Xie et al. 14. Direct Synthesis of para-Diethylbenzene over Modified HZSM-5 Zeolites, Wang Xiangsheng and Guo Hongchen 15. Enhanced para Selectivity in Alkylation and Isomerization Reactions over Silynated ZSM-5 Zeolite, B. S. Rao, R. A. Shaikh, and A. V. Ramaswamy 16. Interaction of P with HY Zeolite and Its Influence on Catalytic Transformation of Alkylbenzene, Huipin
This book investigates the principles and applications of shape-selective catalysis, a field crucial for controlling chemical reactions based on molecular geometry. It explores how the pore structure and surface properties of catalysts, particularly zeolites and molecular sieves, influence reaction pathways and product selectivity. The work details advancements in both fundamental science and industrial applications, focusing on key areas like methanol conversion to gasoline and olefins, and the conversion of monocyclic hydrocarbons.
This collection of chapters, edited by Chunshan Song, presents a comprehensive overview of shape-selective catalysis, drawing on contributions from leading researchers in the field. The detailed chapter titles suggest a focus on fundamental mechanisms, specific catalytic processes, and industrial relevance, particularly concerning zeolites and molecular sieves. The content appears to be aimed at researchers and practitioners in chemistry and chemical engineering, offering insights into controlling reaction outcomes through catalyst design.
Page Count:
352
Publication Date:
1999-01-01
ISBN-10:
0841236194
ISBN-13:
9780841236196
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