The fundamental principles of thermodynamics are applied to understand the behavior of electrified interfaces. This book explores the thermodynamic framework necessary for analyzing electrochemical systems, focusing on the interactions at the interface between an electrode and an electrolyte. It aims to provide a rigorous theoretical foundation for understanding phenomena such as adsorption, corrosion, and electrocatalysis, drawing upon established thermodynamic laws and their specific application to charged surfaces.

The book is recognized as a foundational text for advanced study in electrochemistry and physical chemistry. Its rigorous approach to applying thermodynamic principles to interfacial phenomena makes it a valuable resource for researchers and graduate students. The detailed theoretical treatment provides a deep understanding of the underlying energetic aspects of electrochemical processes. The work is considered a key reference for those seeking to master the thermodynamic underpinnings of electrochemistry.