
For many years it was believed that translational symmetry would be the fundamental property of crystal structures of natural and synthetic compounds. It is now recognised that many compounds crystallise without translational symmetry of their atomic structures. "Incommensurate Crystallography" gives a comprehensive account of the superspace theory for the description of crystal structures and symmetries of these incommensurately modulated crystals and incommensurate composite crystals. It thus provides the necessary background for quantitative analysis of incommensurate crystals by methods in Solid State Chemistry and Solid State Physics. The second half of "Incommensurate Crystallography" is devoted to crystallographic methods of structural analysis of incommensurate compounds. Thorough accounts are given of the diffraction by incommensurate crystals, the choice of parameters in structure refinements, and the use of superspace in analysing crystal structures. The presentation of methods of structure determination includes modern methods like the Maximum Entropy Method and Charge Flipping.
This text investigates the structural properties and symmetry of incommensurately modulated and composite crystals that lack traditional translational symmetry. Sander van Smaalen, a researcher in the field of crystallography, utilizes the framework of superspace theory to provide a rigorous mathematical and physical description of these complex structures. The book serves as a technical manual for applying these theoretical concepts to quantitative structural analysis in solid state chemistry and physics.
What You Will Find
Scope Limits
Experts recognize this work as a primary reference for researchers and graduate students specializing in advanced structural analysis. Readers frequently note the high level of mathematical density and the technical rigor required to fully utilize the methods presented in the text.
Page Count:
288
Publication Date:
2007-01-01
Publisher:
OUP Oxford
ISBN-10:
0191524786
ISBN-13:
9780191524783
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