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Until the 1970s all materials studied consisted of periodic arrays of unit cells, or were amorphous. A new class of solid state matter called aperiodic crystals has since been uncovered. It is a long range ordered structure, but without lattice periodicity. It is found in a wide range of materials: organic and anorganic compounds, minerals (including a substantial portion of the earths crust), and metallic alloys, under various pressures and temperatures. Because of the lack of periodicity, the usual techniques for the study of structure and physical properties no longer work, and new techniques have to be developed.This book deals with the characterisation of the structure, the structure determination and the study of the physical properties, especially dynamical and electronic properties of aperiodic crystals. The treatment is based on a description in a space with more dimensions than three, the so-called superspace. This allows us to generalise the standard crystallography and to look differently at the dynamics. The three main classes of aperiodic crystals, modulated phases, incommensurate composites and quasicrystals are treated from a unified point of view, which stresses similarities of the various systems. The book assumes as a prerequisite a knowledge of the fundamental techniques of crystallography and the theory of condensed matter, and covers the literature at the forefront of the field.Since the first edition of this book in 2007, the field of aperiodic crystals has developed considerably, with the discovery of new materials and new structures. Progress has been made in structure determination, in the interpretation and understanding of the structural characteristics and in the calculation of electrons and phonons. This new edition reflects these new developments, and it includes discussions of natural quasicrystals, incommensurate magnetic and multiferroic structures, photonic and mesoscopic quasicrystals. The second edition also includes a number of
This text investigates the structural characteristics and physical properties of aperiodic crystals, a class of matter that exhibits long-range order without traditional lattice periodicity. The authors, Gervais Chapuis, Marc de Boissieu, and Ted Janssen, utilize the framework of superspace—a multidimensional mathematical approach—to unify the study of modulated phases, incommensurate composites, and quasicrystals. By extending standard crystallographic techniques, the book provides a rigorous methodology for analyzing materials that defy conventional periodic structural models.
What You Will Find
Experts recognize this monograph as a foundational reference for researchers in condensed matter physics and crystallography. Readers frequently note the high level of technical density, which assumes a strong prerequisite background in standard crystallographic theory and solid-state physics.
Page Count:
560
Publication Date:
2018-08-07
Publisher:
Oxford University Press
ISBN-10:
0198824440
ISBN-13:
9780198824442