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Neutral reactive intermediates -- radicals, carbenes, nitrenes, and aryenes -- occupy a fascinating place in the history of organic chemistry. First regarded as mere curiosities, neutral reactive intermediates ultimately came under the intense scrutiny of physical organic chemists from a mechanistic point-of-view. This concise text concentrates on how these electron-deficient species now play a key role in synthetic chemistry research. Important reactions are clearly and simply laid out with carefully chosen examples that illustrate their use in organic synthesis. Each chapter includes problems as well as suggestions for further reading. Undergraduates will find Reactive Intermediates an invaluable summary of this important topic in organic chemistry--one that fills a gap created by the superficial treatment accorded these valuable compounds in most chemistry textbooks.
This text investigates the chemical properties and synthetic utility of neutral reactive intermediates, specifically radicals, carbenes, nitrenes, and aryenes. Authors Christopher J. Moody and Gordon H. Whitham provide a rigorous examination of these electron-deficient species, moving beyond their historical status as chemical curiosities. The book utilizes a mechanistic framework to explain how these intermediates function within modern synthetic chemistry research, bridging the gap between superficial textbook coverage and advanced research applications.
What You Will Find
This primer is widely recognized as a foundational resource for undergraduate chemistry students seeking a focused, high-density overview of reactive intermediates. Experts frequently highlight the text for its clarity and its ability to synthesize complex mechanistic concepts into a concise, accessible format.
Page Count:
96
Publication Date:
1992-08-06
Publisher:
Oxford University Press
ISBN-10:
0198556721
ISBN-13:
9780198556725
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