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This book deals with the electron density distribution in molecules and solids as obtained experimentally by X-ray diffraction. It is a comprehensive treatment of the methods involved, and the interpretation of the experimental results in terms of chemical bonding and intermolecular interactions. Inorganic and organic solids, as well as metals, are covered in the chapters dealing with specific systems. As a whole, this monograph is especially appealing because of its broad interface with numerous disciplines. Accurate X-ray diffraction intensities contain fundamental information on the charge distribution in crystals, which can be compared directly with theoretical results, and used to derive other physical properties, such as electrostatic moments, the electrostatic potential and lattice energies, which are accessible by spectroscopic and thermodynamic measurements. Consequently, the work will be of great interest to a broad range of crystallographers and physical scientists.
This book investigates the relationship between experimental X-ray diffraction data and the underlying electron density distribution in molecules and solids. Philip Coppens, a distinguished researcher in the field of crystallography, provides a rigorous examination of how diffraction intensities serve as a primary source for mapping charge distribution. The text bridges the gap between experimental observation and theoretical chemical bonding models, offering a framework for interpreting physical properties such as electrostatic potential and lattice energies.
What You Will Find
Experts recognize this monograph as a foundational text for understanding the intersection of diffraction physics and chemical bonding theory. Readers frequently note the technical density of the prose, which is intended for advanced students and professional crystallographers in the physical sciences.
Page Count:
384
Publication Date:
1997-05-08
Publisher:
International Union of Crystallography
ISBN-10:
0195098234
ISBN-13:
9780195098235
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