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This book is the first book dealing with structural crystallography of inorganic oxysalts in general. A special emphasis is placed upon structural topology and methods of its description. The latter include graph theory, nets, 2-D and 3-D tilings, polyhedra, etc. The structures considered range from minerals to organically templated oxysalts, for all of which this book provides a unified approach to structure interpretation and classification. Most of the structures have been analysed from the proposed viewpoint for the first time and it has been shown that they possess the same topological genealogy and relationships, sometimes despite their obvious chemical differences. In order to expand the range of oxysalts considered, the book offers not only traditional schemes but also alternative approaches such as anion topologis, anion-centered polyhedra and cation arrays. As such, this book can be considered as a comprehensive introduction into the amazingly complex and diverse world of inorganic oxysalts.
This book investigates the structural topology of inorganic oxysalts to establish a unified framework for their interpretation and classification. Sergey V. Krivovichev, a specialist in mineralogy and crystallography, synthesizes decades of structural data to argue that diverse oxysalt structures share a common topological genealogy. By applying mathematical and geometric principles, the author provides a systematic method for analyzing structures ranging from naturally occurring minerals to synthetic, organically templated compounds.
What You Will Find
Experts recognize this work as a foundational text for researchers in solid-state chemistry and crystallography. Readers frequently note the technical density of the prose, which requires a strong background in structural geometry to fully appreciate the proposed topological methodologies.
Page Count:
320
Publication Date:
2009-03-25
Publisher:
Oxford University Press
ISBN-10:
0199213208
ISBN-13:
9780199213207
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